May Jaleel Abed
University of Al-Qadisiyah, College of Medicine, Medical Chemistry – Iraq
may.abed@qu.edu.iq
Corresponding Author



Ahmed Ebrahim Hamzah
Altoosi University College - Iraq

Kasim Kadhim Alasedi
Altoosi University College - Iraq

Six derivatives of novel triazoles were produced from some substituted benzoic acid with thiocarbazide via method of grinding. The produced Chemicals were described via 1HNMR, IR, and 13CNMR spectra examinations. Produced derivatives of C2H3N3 were examined and assessed as reducing of corrosion in 0.5 M HCl for low-C steel utilizing procedure of losing weight. It was noticed that such chemicals had an encouraging act as reducer counter to mild steel corrosion of in solution being acidic. Reducing of maximum action was assessed at various concentrations and temperature of effector. Competence of corrosion reducer surpassed 96%. The exceptional action was due to inhibitor films adsorption development on surfacing steel. Reducing adsorption on surface of steel tracked Langmuir adsorption isotherm (LAI). The results were long-established BY theoretical calculations of quantum chemistry.

- Arzaee, N. A., Noh, M. F. M., Ab Halim, A., Rahim, M. A. F. A., Ita, N. S. H. M., Mohamed, N. A., ... & Teridi, M. A. M. (2021). Cyclic voltammetry-A promising approach towards improving photoelectrochemical activity of hematite. Journal of Alloys and Compounds, 852, 156757. https://doi.org/10.1016/j.jallcom.2020.156757
- Babić‐Samardžija, K., & Hackerman, N. (2006). Iron corrosion inhibition with dihydrobis‐and hydrotris‐(1‐pyrazolyl) borates. Anti-Corrosion Methods and Materials. https://doi.org/10.1108/00035590610637438
- Blachowicz, T., & Ehrmann, A. (2020). Recent developments of solar cells from PbS colloidal quantum dots. Applied Sciences, 10(5), 1743. https://doi.org/10.3390/app10051743
- Burns, R. M. (1936). The corrosion of metals—I. Mechanism of corrosion processes. Bell System Technical Journal, 15(1), 20-38. https://doi.org/10.1002/j.1538-7305.1936.tb00717.x
- Chauhan, D. S., Quraishi, M. A., Ansari, K. R., & Saleh, T. A. (2020). Graphene and graphene oxide as new class of materials for corrosion control and protection: Present status and future scenario. Progress in Organic Coatings, 147, 105741. https://doi.org/10.1016/j.porgcoat.2020.105741
- Dubas, S. T., & Schlenoff, J. B. (2001). Swelling and smoothing of polyelectrolyte multilayers by salt. Langmuir, 17(25), 7725-7727. https://doi.org/10.1021/la0112099
- Feng, X., Liu, Z., Qin, L., Kang, S. Z., & Li, X. (2020). Photocatalytic activity and the electron transport mechanism of titanium dioxide microsphere/porphyrin implanted with small size copper. Physical Chemistry Chemical Physics, 22(24), 13528-13535. https://doi.org/10.1039/D0CP01953D
- Gan, J., He, J., Hoye, R. L., Mavlonov, A., Raziq, F., MacManus-Driscoll, J. L., ... & Qiao, L. (2019). α-CsPbI3 colloidal quantum dots: synthesis, photodynamics, and photovoltaic applications. ACS Energy Letters, 4(6), 1308-1320. https://doi.org/10.1021/acsenergylett.9b00634
- Gao, J., Wang, X., Zhai, W., Liu, H., Zheng, G., Dai, K., ... & Shen, C. (2018). Ultrastretchable multilayered fiber with a hollow-monolith structure for high-performance strain sensor. ACS applied materials & interfaces, 10(40), 34592-34603. https://doi.org/10.1021/acsami.8b11527
- Georgopoulou, A., & Clemens, F. (2020). Piezoresistive elastomer-based composite strain sensors and their applications. ACS Applied Electronic Materials, 2(7), 1826-1842. https://doi.org/10.1021/acsaelm.0c00278
- Godínez, F. A., Mayén-Mondragón, R., Guzmán, J. E. V., Chávez, O., Gavaises, M., & Montoya, R. (2020). Bioinspired snapping-claw apparatus to study hydrodynamic cavitation effects on the corrosion of metallic samples. Review of Scientific Instruments, 91(6), 066101. https://doi.org/10.1063/5.0007069
- Jones, D. (1992). Principles and prevention of corrosion. Macmillan Publishing Company(USA), 1992,, 568.
- Joy, J., Cheriya, R. T., Nagarajan, K., Shaji, A., & Hariharan, M. (2013). Breakdown of Exciton Splitting through Electron Donor–Acceptor Interaction: A Caveat for the Application of Exciton Chirality Method in Macromolecules. The Journal of Physical Chemistry C, 117(35), 17927-17939. https://doi.org/10.1021/jp403431w
- Khaled, K. F. (2008). Molecular simulation, quantum chemical calculations and electrochemical studies for inhibition of mild steel by triazoles. Electrochimica Acta, 53(9), 3484-3492. https://doi.org/10.1016/j.electacta.2007.12.030
- Lahbib, H., Ben Hassen, S., Gerengi, H., Rizvi, M., & Ben Amor, Y. (2021). Corrosion inhibition performance of dwarf palm and Cynara cardunculus leaves extract for St37 steel in 15% H2SO4: a comparative study. Journal of Adhesion Science and Technology, 35(7), 691-722. https://doi.org/10.1080/01694243.2020.1819701
- Lebrini, M., Bentiss, F., Vezin, H., & Lagrenée, M. (2006). The inhibition of mild steel corrosion in acidic solutions by 2, 5-bis (4-pyridyl)-1, 3, 4-thiadiazole: structure–activity correlation. Corrosion Science, 48(5), 1279-1291. https://doi.org/10.1016/j.corsci.2005.05.001
- Lei, B., Xu, D., Wei, B., Xie, T., Xiao, C., Jin, W., & Xu, L. (2021). In situ synthesis of α-Fe2O3/Fe3O4 heterojunction photoanode via fast flame annealing for enhanced charge separation and water oxidation. ACS applied materials & interfaces, 13(3), 4785-4795. https://doi.org/10.1021/acsami.0c19927
- Li, M., Zang, S., Wang, Y., Li, J., Ma, J., Zhang, X., & Liu, Y. (2021). Facile sputtering enables double-layered ZnO electron transport layer for PbS quantum dot solar cells. Solar Energy, 214, 599-605. https://doi.org/10.1016/j.solener.2020.11.042
- Li, Y., Lu, X., Wu, K., Yang, L., Zhang, T., & Wang, F. (2020). Exploration the inhibition mechanism of sodium dodecyl sulfate on Mg alloy. Corrosion Science, 168, 108559. https://doi.org/10.1016/j.corsci.2020.108559
- Liu, H., Wang, H., Qian, Y., Zhuang, J., Hu, L., Chen, Q., & Zhou, S. (2019). Nitrogen-doped graphene quantum dots as metal-free photocatalysts for near-infrared enhanced reduction of 4-nitrophenol. ACS Applied Nano Materials, 2(11), 7043-7050. https://doi.org/10.1021/acsanm.9b01549
- Mehta, H., Kaur, G., Chaudhary, G. R., & Prabhakar, N. (2021). Assessment of bio-corrosion inhibition ability of Hafnium based cationic metallosurfactant on iron surface. Corrosion Science, 179, 109101. https://doi.org/10.1016/j.corsci.2020.109101
- Messali, M., Larouj, M., Lgaz, H., Rezki, N., Al-Blewi, F. F., Aouad, M. R., ... & Chung, I. M. (2018). A new schiff base derivative as an effective corrosion inhibitor for mild steel in acidic media: Experimental and computer simulations studies. Journal of Molecular Structure, 1168, 39-48. https://doi.org/10.1016/j.molstruc.2018.05.018
- Onyeachu, I. B., & Solomon, M. M. (2020). Benzotriazole derivative as an effective corrosion inhibitor for low carbon steel in 1 M HCl and 1 M HCl+ 3.5 wt% NaCl solutions. Journal of Molecular Liquids, 313, 113536. https://doi.org/10.1016/j.molliq.2020.113536
- Tom, A. E., Thomas, A., & Ison, V. V. (2020). Novel post-synthesis purification strategies and the ligand exchange processes in simplifying the fabrication of PbS quantum dot solar cells. RSC Advances, 10(51), 30707-30715. https://doi.org/10.1039/D0RA05242F
- Wang, M. C., Sheng, G. D., & Qiu, Y. P. (2015). A novel manganese-oxide/biochar composite for efficient removal of lead (II) from aqueous solutions. International Journal of Environmental Science and Technology, 12(5), 1719-1726. https://doi.org/10.1007/s13762-014-0538-7
- Xing, M., Wei, Y., Wang, R., & Zhang, Z. (2021). Study on the performance of ZMO/PbS quantum dot heterojunction solar cells. Solar Energy, 213, 53-58. https://doi.org/10.1016/j.solener.2020.11.023
- Xiong, Y., Yang, L., Zhu, Y., Lai, Q., Li, P., Xiao, P., & Cao, G. (2021). Tuning Electronic Structure of 2D In2S3 via P Doping and Size Controlling Toward Efficient Photoelectrochemical Water Oxidation. Solar RRL, 5(1), 2000618. https://doi.org/10.1002/solr.202000618
- Yang, F., Ke, Z., Li, Z., Patrick, M., Abboud, Z., Yamamoto, N., ... & Gu, J. (2020). Photo/Bio‐Electrochemical Systems for Environmental Remediation and Energy Harvesting. ChemSusChem, 13(13), 3391-3403. https://doi.org/10.1002/cssc.202000203
- Younis, S. A., Kwon, E. E., Qasim, M., Kim, K. H., Kim, T., Kukkar, D., ... & Ali, I. (2020). Metal-organic framework as a photocatalyst: Progress in modulation strategies and environmental/energy applications. Progress in Energy and Combustion Science, 81, 100870. https://doi.org/10.1016/j.pecs.2020.100870
- Zhang, R., Li, S., Ying, C., Hu, Z., Lv, A., Hu, H., ... & Wong, C. P. (2020). Bioinspired design of flexible strain sensor with high performance based on gradient filler distributions. Composites Science and Technology, 200, 108319. https://doi.org/10.1016/j.compscitech.2020.108319
- Zhu, H., Li, X., Lu, X., Chen, X., Li, J., Han, X., ... & Hu, Z. (2021). Intra-/inter-molecular synergistic inhibition effect of sulfonate surfactant and 2-benzothiazolethiol on carbon steel corrosion in 3.5% NaCl solution. Corrosion Science, 182, 109291. https://doi.org/10.1016/j.corsci.2021.109291


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How to Cite:
Abed, M. J., Hamzah, A. E., & Alasedi, K. . K. (2022). Synthesis and Characterization of New Triazols Derivatives as C-Steel Reducing of Corrosion in Acidic Medium. Biomedicine and Chemical Sciences, 1(3), 178–192. https://doi.org/10.48112/bcs.v1i3.126
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